Date of Submission
Academic Programs and Concentrations
Project Advisor 1
Multi-dentate thiophene-derived imine ligands, with a cyclohexyl backbone containing a variety of stereocenters, were synthesized and then subsequently reacted with the binuclear platinum compound, [Pt2Me4(µ-SMe2)2], to afford cyclometalated platinum(II) species with C^N^N pincer-type ligands. The complexes were characterized by NMR, IR, UV/vis, and emission spectroscopy. The complexes’ reactions with methyl iodide were explored to determine the stereospecificity of the oxidative addition reaction to form platinum(IV) species.
Open Access Agreement
Creative Commons License
This work is licensed under a Creative Commons Attribution-Noncommercial-No Derivative Works 3.0 License.
Sarabia, Julienne Aldeano, "Synthesis and Characterization of Platinum (II) Complexes with Thiophene-Based Ligands" (2015). Senior Projects Spring 2015. 166.
This work is protected by a Creative Commons license. Any use not permitted under that license is prohibited.Bard Off-campus Download
Bard College faculty, staff, and students can login from off-campus by clicking on the Off-campus Download button and entering their Bard username and password.