Date of Submission
Spring 2015
Academic Programs and Concentrations
Chemistry
Project Advisor 1
Craig Anderson
Abstract/Artist's Statement
Multi-dentate thiophene-derived imine ligands, with a cyclohexyl backbone containing a variety of stereocenters, were synthesized and then subsequently reacted with the binuclear platinum compound, [Pt2Me4(µ-SMe2)2], to afford cyclometalated platinum(II) species with C^N^N pincer-type ligands. The complexes were characterized by NMR, IR, UV/vis, and emission spectroscopy. The complexes’ reactions with methyl iodide were explored to determine the stereospecificity of the oxidative addition reaction to form platinum(IV) species.
Creative Commons License
This work is licensed under a Creative Commons Attribution-Noncommercial-No Derivative Works 3.0 License.
Recommended Citation
Sarabia, Julienne Aldeano, "Synthesis and Characterization of Platinum (II) Complexes with Thiophene-Based Ligands" (2015). Senior Projects Spring 2015. 166.
https://digitalcommons.bard.edu/senproj_s2015/166
This work is protected by a Creative Commons license. Any use not permitted under that license is prohibited.
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