Date of Submission
Spring 2015
Academic Programs and Concentrations
Chemistry
Project Advisor 1
Craig Anderson
Abstract/Artist's Statement
Multi-dentate thiophene-derived imine ligands, with a cyclohexyl backbone containing a variety of stereocenters, were synthesized and then subsequently reacted with the binuclear platinum compound, [Pt2Me4(µ-SMe2)2], to afford cyclometalated platinum(II) species with C^N^N pincer-type ligands. The complexes were characterized by NMR, IR, UV/vis, and emission spectroscopy. The complexes’ reactions with methyl iodide were explored to determine the stereospecificity of the oxidative addition reaction to form platinum(IV) species.
Open Access Agreement
On-Campus only
Creative Commons License
This work is licensed under a Creative Commons Attribution-Noncommercial-No Derivative Works 3.0 License.
Recommended Citation
Sarabia, Julienne Aldeano, "Synthesis and Characterization of Platinum (II) Complexes with Thiophene-Based Ligands" (2015). Senior Projects Spring 2015. 166.
https://digitalcommons.bard.edu/senproj_s2015/166
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