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Cyclometalated Pt compounds were formed through C-H activation or C-X activation using brominated and non-brominated thiophene-based ligands. The ligands were combined with the much utilized platinum precursor, cis-[Pt2Me4(μ-SMe2)2] and through a variety of oxidative addition and/or reductive elimination reactions Pt(II) and Pt(IV) complexes were isolated. Compounds were characterized by multi-nuclear NMR spectroscopy. In several cases, diastereomeric mixtures of platinum(IV) compounds were observed. Thermolysis reactions of the Pt(IV) compounds resulted in new mixtures of platinum(II) products.
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Yu, David, "C-H AND C-X ACTIVATION OF BROMINATED AND NON-BROMINATED IMINE LIGANDS TO FORM Pt(IV) AND Pt(II) CYCLOMETALATED COMPLEXES" (2017). Senior Projects Spring 2017. 64.
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